氧分析儀

氧分析儀在燃燒控制、製程質量、安全和環保應用中提供有價值的測量。其應用場景廣泛,涵蓋電廠鍋爐燃燒優化、煉油和石化廠加熱爐效率提升、排放管道的工業安全監測,以及乙烯生產中的質量控制等領域。

橫河電機提供一系列產品解決方案,包括氧化鋯氧探頭系列及可調諧二極管激光光譜儀。

應用

  可調諧二極管激光氣體分析儀
TDLS

氧化鋯型(濃差電池系統)
ZR/ZS
氧化鋯型(限流型)
OX
順磁式
MG
燃燒控制/流程管理  
半導體/電子元件/制造工業      
含有易燃氣體的測量    
無需採樣  
防爆設計  

>> 請查看氧分析儀的測量系統

Details

氧分析儀測量系統及其優缺點

我們目前銷售的氧分析儀的測量系統如下。

氧化鋯型測量系統:

  • 濃差電池系統:ZR22G/ZR802、ZR202G、ZR202S 和 OX400
  • 限流型:OX100和OX102

順磁式測量系統:

  • 順磁系統:MG8G和MG8E

可調諧二極管激光測量系統:

  • 可調諧二極管激光測量系統:TDLS8000、TDLS8100、TDLS8200

由於每種測量系統都有自己的優點和缺點,因此選擇適合您的應用和預期用途的氧分析儀非常重要。以下是每種測量系統及其優缺點的概述。


氧化鋯型測量系統

濃差電池系統

氧化鋯等固體電解質在高溫下具有氧離子導電性。如下圖所示,當在加熱的氧化鋯元件兩側附著多孔鉑電極,並使不同氧分壓的氣體分别接觸氧化鋯表面時,該裝定將作為氧濃差電池工作。根據能斯特方程,這種現象會在兩個電極之間產生電動勢。

Concentration cell system

優點

  • 可直接安裝在鍋爐煙道等燃燒製程中,無需採樣系統,且響應速度更快(ZR22G、ZR202G)
  • 能夠測量微量氧濃度(OX400)

缺點

  • 如果樣氣中含有易燃氣體,則會產生測量誤差(完全燃燒的廢氣通常無此問題)。

限流型

如下圖所示,若限制高溫氧化鋯元件陰極側的氧氣流入,即使施加電壓增加,電流也會進入恒定區域。該受限電流與氧濃度成正比。

Limiting Current type

優點

  • 能夠測量微量氧濃度
  • 僅在量程側(空氣)需要校準

缺點

  • 如果樣氣中含有易燃氣體,則會產生測量誤差。
  • 粉塵會導致陰極側氣體擴散孔堵塞,需前定製濾器。

磁性測量系統

順磁系統

此方法利用氧氣的順磁性。當樣氣含氧時,氧氣被吸入磁場,導致流路B中的輔助氣體流量減少。流路A與B的流量差(由流路B的限流作用引起)與樣氣氧濃度成正比。流量通製熱敏電阻檢測並轉換為電信號,其差值作為氧信號輸出。

Paramagnetic system

優點

  • 可測量氧化鋯氧分析儀無法檢測的易燃混合氣體。
  • 檢測部無接觸樣氣的傳感器,可測量腐蝕性氣體。
  • 在磁性類型中,順磁系統響應速度更快。
  • 在磁性類型中,順磁系統的抗振動/衝擊能力更強。

缺點

  • 需根據樣氣特性或應用配定採樣單元。

可調諧二極管激光測量系統

可調諧二極管激光測量系統

可調諧二極管激光(TDL)測量基於吸收光譜技術。TruePeak分析儀作為TDL系統,通製測量激光穿製被測氣體時的光吸收(損耗)量進行監測。簡化的TDL分析儀由以下組件構成:產生紅外光的激光器;光學透鏡組,用於將激光聚焦穿製待測氣體並投射到探測器上;探測器;控制激光的電子元件,並將探測器信號轉換為代表氣體濃度的輸出信號。

氣體分子會吸收特定波長的光,稱為吸收譜線。這種吸收遵循比爾定律。
TDL分析儀本質上是符合比爾-朗伯定律的紅外分析儀,其公式為:

I = Io e-EGL
其中:
I = 吸收後的輻射強度
Io = 初始輻射強度
E = 消光系數
G = 氣體濃度
L = 測量路徑長度

橫河電機的型號:TDLS8000

Tunable Diode Laser measurement system

優點

  • 可在複雜工況中測量多種近紅外吸收氣體。
  • 支持高溫、高壓、嚴苛條件(腐蝕性、侵蝕性、高顆粒環境)下測量。
  • 多數應用為原地測量,降低安裝維護成本。
  • 多數測量快速(5秒)且無干擾。

缺點

  • 需預先安裝法蘭接口。

參考

摘要:
  • Yokogawa's CENTUM CS 3000 DCS Monitors and Controls Operations at Poultry Litter-to-energy Plant
  • The boiler and turbine startup procedures reduces operator workload and helps to ensure a smooth and safe startup
摘要:

If a sensor is not operating, the manufacturer cannot detect moisture in the chlorine and must stop the process. Unfortunately, sensors can deteriorate and deliver inaccurate measurements due to contact with the process.

摘要:

A furnace for heating slabs needs to be operated under low oxygen conditions at high temperatures of 1000°C and above to prevent oxidation of the steel. The measurement of oxygen concentrations in the furnace is essential in this process. (AN 10M01F01-03E)

摘要:

The ammonia (NH3) gas is injected to remove the NOx and thus reduce the NOx concentration in the stack flue gas. With conventional NH3 analyzers that perform measurements indirectly, NH3 concentrations are obtained through a sampling system. Therefore, there are problems with the maintenance and running costs of the sampling system, and time delays in measurement. The TDLS8000 Laser Analyzer is the solution to all these problems.

摘要:

O2 measurement in hydrocarbon vapor is used for safety monitoring in vacuum distillation columns in petroleum refining. With conventional paramagnetic oxygen analyzers, O2 concentrations are obtained through an extractive sampling system, which conditions the sample prior to being analyzed.

摘要:

In a hot blast stove, the by-product gas produced in a coke oven is burned to preheat the air blast for the blast furnace. To improve the combustion efficiency and conserve energy in a hot blast stove, it is essential to be able to control combustion by measuring and adjusting the oxygen concentration in the exhaust gases.

摘要:

A package boiler operates more efficiently if the oxygen concentration in the flue gas is reduced. Optimizing air intake for boiler operation requires continuous measurement of the oxygen concentration in the flue gas.

摘要:

Combustion furnaces such as heating furnaces and boilers in plants include various sizes and types, and serve as energy sources, that is, they are cores in all production activities. Because a large amount of fuel such as gas or fuel oil is consumed in plants, their combustion efficiency directly affects the performance and running cost of the plants. 

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