Liquid Analyzers for Electrolysis Plants

Download (740 KB)

Introduction

Process liquid analyzers such as pH meters, conductivity meters, ORP meters, and density meters play an important role at electrolysis plants in the control of concentrations of various process solutions. This requires both precision and stability under harsh conditions that include highly corrosive substances, high temperatures, and many impurities.

Expected Benefits

  • Ensures stable, continuous measurement in heavily contaminated liquids
  • Reduces operating costs
  • Eliminates the need for manual cleaning

List of Analyzers

Type Measurement point Objective
pH meter 1) Supersaturated brine at raw salt dissolver outlet *1 pH control for impurity removal in brine Control value: 10.8 to 11.0 pH
2) Refined brine *2 Control of precipitation of impurities Acid range
3) Brine at electrolysis tank inlet *3 pH control of electrolysis tank brine inflow: 3 to 6 pH
4) Return brine at electrolysis tank outlet *4 Efficiency control in dechlorination tank Acid range
5) Desalinated water at dechlorination tank outlet *5 Desalinated water control
6) Hydrochloric acid plant drainage *6 Drainage control
Conductivity meter 1) Supersaturated brine at electrolysis tank outlet *7 Brine concentration control: concentration: 300 to 320 g/l
2) Refined brine *8 Refined brine concentration control
3) Sulfuric acid concentration used for drying in chlorine gas drying line *9 Concentration control of recovered sulfuric acid: approximately 74 %
4) Hydrochloric acid concentration in hydrochloric acid plant *10 Hydrochloric acid concentration control: approximately 35 wt%
5) Sodium hypochlorite concentration in a soda hypochlorite plant *11 Sodium hypochlorite concentration control:
Available chlorine: 10 to 15 %
Residual caustic soda: 0.1 to 1% (approximately 10 g/l)
Oxidation reduction Potential (ORP) meter 1) Desalinated water at dechlorination tank outlet *12 Confirmation of dechlorination reaction
2) Soda hypochlorite plant adsorption tank outlet *13 End control of caustic soda chlorination reaction
Vibration type liquid density meter 1) Anode solution at electrolysis tank outlet *14 Anode solution caustic soda concentration control
2) Caustic soda concentration at concentrate drum outlet *15 Product caustic soda concentration control

Solution Details

Solution Details

Solution Details

Conclusion

Yokogawa process solution analyzers deliver stable, long-term measurements under the harsh conditions present in electrolysis plants. The FLXA202/FLXA21 Inductive Conductivity Meter is specially designed to detect the concentrations of hydrochloric acid, sulfuric acid, and caustic soda. The PH4C pH Sensor for Chemical Processes can measure pH in a wide variety of processes.

Field Data

Each graph shows a correlation between concentration and conductivity at measurement points, the numbers of which correspond to the ones in the previous page. The ISC inductive conductivity meter's range can be specified, thereby allowing high-resolution measurements in the target concentration range.

Measurement point: 7, 11, 13
 

The correlation between concentration and conductivity is largely affected by solution temperature. The ISC inductive conductivity meter provides automatic temperature compensation using the build-in temperature sensor.

Measurement point: 9, 10

Industries

  • Chemical

    Chemical plants rely on continuous and batch production processes, each posing different requirements for a control system. A continuous process calls for a robust and stable control system that will not fail and cause the shutdown of a production line, whereas the emphasis with a batch process is on having a control system that allows great flexibility in making adjustments to formulas, procedures, and the like. Both kinds of systems need to be managed in available quality history of product, and to be able to execute non-routine operations. With its extensive product portfolio, experienced systems engineers, and global sales and service network, Yokogawa has a solution for every plant process.

    See More
  • Specialty & Fine Chemical

    Yokogawa has long served customers in the specialty and fine chemicals market. With a market leading batch solution that offers the best in class reliability and flexibility as well as industry experts who understand the complex requirements in designing a batch solution, you can be assured that in your partnership with Yokogawa you will have a system that will enable you to produce products that meet your customers’ needs in the future while maintaining safety and regulatory compliance.

    See More

Related Products & Solutions

  • 2-Wire Transmitter/Analyzer FLXA202

    The FLEXA™ series analyzers are used for continuous on-line measurements in industrial installations. With an option for single or dual sensor measurement, they are the most flexible two-wire analyzer available.

    See More
  • 2-Wire Transmitter/Analyzer FLXA21

    The FLEXA™ series analyzers are used for continuous on-line measurements in industrial installations. With an option for single or dual sensor measurement, they are the most flexible two-wire analyzer available.

    See More
  • Contacting Conductivity Sensors SC42/SC4A(J)

    The measurement of specific conductivity in aqueous solutions is becoming increasingly important for the determination of impurities in water.  Yokogawa has designed a full range of precision sensors and instruments to cope with these measurements, even under extreme conditions.

    See More
  • Digital SMART SENCOM™ Adapter, SA11

    Reusable SMART adapter, requiring only the analog sensor to be disposed of when it reaches the end of its lifetime. With the SENCOM 4.0 platform, Yokogawa delivers reduced costs and waste while contributing to its long-term business goals of a sustainable future for all.

    See More
  • Flow/NPT Fittings FF20/FS20

    Yokogawa has invested considerable design and development time in producing a full range of fittings with particular emphasis on designs that reduce installation and maintenance time and consequently save operation costs.

    See More
  • Hot-Tap Holder PR10

    On-line measurements often present extra challenges, especially when routine maintenance is required. The PR10 is ideally suitable for applications where the sensors must be removed without interrupting or shutting down the process. Without any special tools the PR10 can be retracted safely from the process at pressures up to 5 bar (72 psi). Using the PR10 allows us to place any dissolved oxygen sensor that has a PG13.5 connenction into a retractable assembly.

    See More
  • Industrial pH/ORP Electrodes

    The heart of a pH measuring loop is the electrode system. Yokogawa has designed a wide range of electrodes to ensure this heart keeps beating under the most severe conditions.

    See More
  • InfraSpec NR800

    NR800 is a FT-NIR analyzer offering unparalleled reliability and stability for a wide range of process and laboratory applications from Yokogawa. Its high wavelength resolution, outstanding accuracy and wide scanning range deliver a new level of process information, opening up new possibilities. Direct transfer of a calibration model from the laboratory to the process, or among processes, is also possible. And of course, ease of operation and user-friendly software are key design concepts of the NR800.

    See More
  • Liquid Density Analyzer DM8C, VD6

    The DM8 liquid density analyzer measures liquid density of general process liquids with high sensitivity and excellent stability. It has a measuring density range of 0 to 2.0 g/cm3, and unaffected by flow rate and viscosity. Besides general-purpose sensor, sanitary and explosionproof sensor are also available.

    See More
  • Liquid Density Analyzer

    The DM8 liquid density analyzer measures liquid density of general process liquids with high sensitivity and excellent stability. It has a measuring density range of 0 to 2.0 g/cm3, and unaffected by flow rate and viscosity. Besides general-purpose sensor, sanitary and explosionproof sensor are also available.

    See More
  • pH and ORP Sensors

    pH electrodes and sensors are the sensing portions of a pH measurement. Various installation options including retractable, flow thru, immersion, and direct insertion. Proper pH electrode/sensor selection is critical for optimal measurement results.

    See More

Top